[VO(PS-BBMA)](SO4) catalyzed α-oxygenation of benzylamines to amides in solvent free condition

Synthesis of Some Biginelli-type Products: Nano Alumina Sulfonic acid (NASA) Catalyzed under Solvent-free Condition

Biginelli-type reaction was developed by means of a three-component condensation of analdehyde, ethyl acetoacetate, urea or thiourea and nano alumina sulfonic acid (Al2O3-SO3H)(NASA) as catalyzed. It is carried out under different conditions. In all conditions, the desiredproducts are obtained in high yields after relatively short reaction times. Nevertheless, thereactions proceeded faster and ...

CuCl2 Catalyzed Solvent-free One Pot Synthesis of Dihydropyrimidinones

Natural Acid Catalyzed Synthesis of Schiff Base under Solvent-free Condition: As a Green Approach

The reaction of primary aromatic amines with aryl aldehydes is found to be catalyzed by lemon juice as natural acid under solvent-free conditions to give the corresponding Schiff bases in good yields. This eco-friendly reaction has many advantages like economical, environmental, mild reaction conditions and simple work-up with high product yield.

Highly Efficient Acetalization and Ketalization Catalyzed by Cobaloxime under Solvent-Free Condition

An efficient catalytic system was developed for the acetalization and ketalization of carbonyl compounds with polyhydric alcohols under mild solvent-free conditions. In the presence of 0.1 mol% CoCl2 and 0.2 mol% dimethylglyoxime at 70 ◦C under 5 KPa pressure for 1 h, 95.3% conversion of cyclohexanone and 100% selectivity of the corresponding cyclic ketal could be obtained, where TOF reached as...

SYNTHESIS OF 1,8-DIOXO-OCTAHYDROXANTHENES WITH THIAMINE CHLORIDE IN ECO-FRINDLY AND SOLVENT FREE CONDITION

A novel, simple and environmentally friendly method is reported for the preparation of 1,8-dioxo-octahydroxanthene derivatives by the reaction of dimedon with various aromatic aldehydes, using thiamine chloride  as a recyclable catalyst under solvent-free conditions. This procedure has following benefits; simple workup, moderate reaction times, good yields, and completely compatible with enviro...